Landfill Siloxane Gas Sensing Using Differentiating, Responsive Phase Coated Microcantilever Arrays

Landfill biogases are being utilized more frequently as a new source of fuel energy. Volatile siloxane compounds usually contained in landfill biogases will form siloxane residues when the gases are burned, which significantly increases abrasion of combustion engines. Research on detection of siloxanes in landfill gas has been active during recent years with the principal analytical technique being gas chromatography/mass spectrometry (GC/MS). In our present work, we introduce a less expensive, compact methodology that employs microcantilever (MC) arrays for sensitive nanomechanical-based gas-phase sensing of the siloxanes. The cantilevers on the MC array were differentially coated on the active, nanostructured side with different responsive phases, and composite responses (magnitude of siloxane-induced MC bending) for four siloxanes were collected that exhibited selective signatures to aid in recognizing each siloxane. Limits of detection (LODs) derived from linear calibration plots were down to the sub-parts-per-million range, a sensitivity that is comparable with that of GUMS reported by other researchers. Studies were performed in rather inert helium environment and a realistic matrix, and the overall response profiles and LODs were similar for both matrixes. A 5 week long-term reproducibility study illustrates the stability of the MC array. Moreover, the portable character of the MC array setup makes our method a very promising way to facilitate in-field detection of siloxanes in landfill gas in the future.