Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 45, Issue 13, Pages 2601-2608Publisher
WILEY-BLACKWELL
DOI: 10.1002/pola.22017
Keywords
hydrogel; ABC triblock; ATRP; fluoropolymer; ethylene glycol
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New ABC triblock copolymers that contain lipophilic, hydrophilic, and fluorophilic blocks are reported. These new block copolymers were synthesized via sequential controlled/living atom transfer radical polymerization. The formation of block copolymers was confirmed by size exclusion chromatography, H-1, and F-19 NMR. In direct comparison to the ABC copolymer, the corresponding ABA' polymer did not produce a gel up to 45 wt % polymer. (c) 2007 Wiley Periodicals, Inc.
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