Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 349, Issue 10, Pages 1725-1737Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200700039
Keywords
enhanced Lewis acidity; Friedel-Crafts; alkenylation; hydroarylation; ionic liquids containing non-coordinating anions; vinyl cation intermediates
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Funding
- National Research Foundation of Korea [R11-2005-008-02002-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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In the metal triflate-catalyzed hydroarylation of alkynes, employing an ionic liquid dramatically enhanced the catalytic activities, resulting in broadening the scope of substrates (arenes and alkynes). In some cases, even reactions that were not possible in conventional organic solvents proceeded smoothly in ionic liquids. Moreover, the ionic liquid phase containing catalyst could be readily recovered by simple decantation of the organic layer after reaction and reused for the following runs without any significant loss of activity. Mechanistic studies including C-13 NMR analysis of reaction intermediates and isotope experiments confirmed for the first time that this type of reaction proceeds via vinyl cationic intermediates.
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