Journal
BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS
Volume 1767, Issue 7, Pages 883-887Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.bbabio.2007.04.004
Keywords
complex III; cytochrome bc(1); semiquinone Qo; superoxide; electron transfer
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Funding
- NIGMS NIH HHS [R01 GM027309, GM 27309] Funding Source: Medline
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Complex III Qo site semiquinone has been assigned pivotal roles in productive energy-conversion and destructive superoxide generation. After a 30-year search, a genetic heme b(H) knockout arrests this transient semiquinone EPR radical, revealing the natural engineering balance pitting energy-conserving, short-circuit minimizing, split electron transfer and catalytic speed against damaging oxygen reduction. (C) 2007 Elsevier B.V. All rights reserved.
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