Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 128, Issue 7, Pages 762-768Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2007.04.017
Keywords
fluorine-containing lithium 1,3-diketonates; fluorine-containing enaminoketones; crown-ethers; podands; X-ray crystallography
Categories
Ask authors/readers for more resources
Fluorinated enaminoketones, a new type of ligands, bearing two independent coordination centers (polyether's and fluorinated enaminoketones fragments) have been obtained. The crystal structure of the Cu(II) complex of 1,5-bis-[2-(4,4',4'-trifluoro-1'-methyl-3-oxo-but-1'-enylamino)-phenoxy]-3-oxapentane (10) has been elucidated by X-ray crystallography. The results obtained show that the complex 10 consists of two crystallographically independent molecules C26H24CuF6N2O5 (A and B), and the metal atom in the complex 10 has four-coordinated arrangement, as a polyhedron with a distorted square with two nitrogen and two oxygen atoms located in corners. (c) 2007 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available