4.5 Article

Gold(I) pyrenyls: Excited-state consequences of carbon-gold bond formation

Journal

ORGANOMETALLICS
Volume 26, Issue 14, Pages 3279-3282

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om700346v

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Two 1-pyrenyl derivatives of gold(I) have been prepared by base-promoted transmetalation of 1-pyreneboronic acid. Triplet-state luminescence observed from the new complexes at 77 K is assigned to a pyrene pi-pi* state.

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