Journal
TETRAHEDRON LETTERS
Volume 48, Issue 27, Pages 4691-4694Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.05.007
Keywords
(R)-deoxydydibetaine; (-)-4-epi-dysibetaine; samarium iodide; reductive carbon-nitrogen bond cleavage; alpha,alpha-disubstituted; amino acid
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Enantioselective synthesis of (R)-deoxydysibetaine and (-)-4-epi-dysibetaine was achieved by employing a samarium iodide-promoted reductive carbon-nitrogen bond cleavage of a proline derivative, as a key reaction. (c) 2007 Elsevier Ltd. All rights reserved.
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