Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 272, Issue 1-2, Pages 293-297Publisher
ELSEVIER
DOI: 10.1016/j.molcata.2007.03.055
Keywords
supported palladium catalyst; MCM-41; sonogashira coupling; aryl iodide; heterogeneous catalysis
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The MCM-41 -supported thioether palladium(0) complex is a highly active catalyst for the copper-free Sonogashira coupling of aryl iodides with terminal alkynes in water at room temperature under aerobic conditions. This phosphine-free heterogeneous palladium catalyst can be easily recovered from the products and reused many times without loss of activity. (C) 2007 Elsevier B.V. All rights reserved.
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