4.5 Article

C-H bond activation by water on a palladium or platinum metal surface

Journal

SYNTHESIS-STUTTGART
Volume -, Issue 13, Pages 2055-2059

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-2007-983738

Keywords

platinum; deuterium; carbazole; water; hydrothermal; hydrogenation

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A water molecule is partially cleaved on a palladium or platinum metal surface under hydrothermal conditions to form an active platinum species. The species is effective for C-H bond functionalization which can be applied for H/D-exchange reactions, CC bond-forming reactions, and C-N bond-forming reactions.

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