4.3 Article

An effect of structural modification in the photo-hydrogen-evolving RuIIPtII dimers

Journal

CHEMISTRY LETTERS
Volume 36, Issue 7, Pages 920-921

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2007.920

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The second example of a photo-hydrogen-evolving (PHE) molecular device consisting of a Ru(bpy)(3)(2+) (bpy = 2,2'-bipyridine) derivative and a cis-PtCl2 unit has been successfully prepared and characterized to reveal that the PHE activity is quite sensitive to the structural modification at the bridging spacer unit connecting the Ru-II and Pt-II centers.

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