Journal
ORGANIC LETTERS
Volume 9, Issue 14, Pages 2721-2724Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol071038k
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Radicals can be regarded as electrophilic/nucleophilic, depending on their tendency to attack sites of relatively higher/lower electron density. In this paper, an electrophilicity scale, global as well as local, and a nucleophilicity scale for 35 radicals is reported. The global electrophilicity scale correlates well with the nucleophilicity scale, suggesting that these concepts are inversely related.
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