4.8 Article

Three-dimensional imaging of colloidal glasses under steady shear

Journal

PHYSICAL REVIEW LETTERS
Volume 99, Issue 2, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.99.028301

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Funding

  1. Engineering and Physical Sciences Research Council [EP/D071070/1, GR/S10377/01, EP/D067650/1] Funding Source: researchfish
  2. EPSRC [EP/D071070/1, EP/D067650/1] Funding Source: UKRI

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Using fast confocal microscopy we image the three-dimensional dynamics of particles in a yielded hard-sphere colloidal glass under steady shear. The structural relaxation, observed in regions with uniform shear, is nearly isotropic but is distinctly different from that of quiescent metastable colloidal fluids. The inverse relaxation time tau(-1)(alpha) and diffusion constant D, as functions of the local shear rate (gamma) over dot, show marked shear thinning with tau(-1)(alpha)proportional to D proportional to (gamma) over dot(0.8) over more than two decades in (gamma) over dot. In contrast, the global rheology of the system displays Herschel-Bulkley behavior. We discuss the possible role of large scale shear localization and other mechanisms in generating this difference.

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