Journal
ANALYTICAL CHEMISTRY
Volume 79, Issue 14, Pages 5444-5448Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ac070751k
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A general strategy to localize and quantify carbon-centered radicals within proteins is described. The methodology was first exemplified on amino acids and then on a peptide. This method is applicable to any protein system regardless of size, and the site of hydrogen abstraction by (OH)-O-center dot on all residues within proteins is easily and accurately detected.
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