Journal
ORGANIC LETTERS
Volume 9, Issue 15, Pages 2763-2766Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol070971k
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- NIGMS NIH HHS [GM33049] Funding Source: Medline
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Spirotryprostatin B was synthesized in eight steps, utilizing an efficient palladium-catalyzed prenylation reaction to construct the quaternary C3 stereocenter. The decarboxylation-alkylation of a series of substituted beta-keto esters is described, demonstrating the broad scope of this class of pronucleophiles and allylating agents.
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