Journal
TETRAHEDRON
Volume 63, Issue 30, Pages 6996-7002Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2007.05.035
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An enantiospecific coupling of propargylic esters and carbonates with arylboronic acids has been developed using a palladium catalyst. Optically active 1,3-disubstituted allenes were synthesized with high enantiomeric excesses by carrying out the reactions under basic aqueous conditions. (C) 2007 Elsevier Ltd. All rights reserved.
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