Journal
TETRAHEDRON LETTERS
Volume 48, Issue 30, Pages 5255-5260Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.05.137
Keywords
trifluorinated compounds; 1,1-dichloro-1-alkene; super-acid; HF-SbF5
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A two step process for converting ketone or aldehyde via 1,1-dichloro-1-alkenes to the corresponding 1,1,1-trifluoro-derivatives is described, based on HF addition and chlorine-fluorine exchange under superacidic conditions. (c) 2007 Elsevier Ltd. All rights reserved.
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