Journal
SYNLETT
Volume -, Issue 12, Pages 1799-1822Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2007-984538
Keywords
chirality; asymmetric synthesis; enantiomeric resolution; kinetic resolution; coupling
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Funding
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0718117] Funding Source: National Science Foundation
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Compounds with highly annelated, chiral pi.-systems, such as tetraphenylenes and [n]helicenes, are known to possess strong chiral properties and high configurational stability, which are prerequisites for many chiral materials. This account describes the unfolding story about our research on the synthesis and X-ray crystallographic characterization of functionalized nonracemic tetraphenylenes and helical beta-oligothiophenes, as well as related [n]helicene derivatives.
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