Journal
MACROMOLECULES
Volume 40, Issue 15, Pages 5290-5293Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma070795v
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The synthesis of two new water-soluble, carboxylate-substituted poly(p-phenyleneethynylene)s (PPE) is reported. These PPEs differ in their concentration of free carboxylate groups per repeat (two aryleneethynylenes) unit. The photophysical properties of these two polymers are compared to each other and to that of the known dicarboxylate-PPE. An increasing concentration of carboxylate groups (on a per repeat basis) makes the polymers less fluorescent but also more sensitive toward quenching by mercury ions. The least carboxylate functionalized PPE shows the highest quantum yield (0.33). All three PPEs are pH-sensitive and show dramatic changes in absorption and emission at around pH 3.5, which is the pK(a) of methoxyacetic acid, the common structural subunits in all of these PPEs.
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