Journal
MACROMOLECULES
Volume 40, Issue 15, Pages 5337-5343Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma0701134
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The use of copper(I)-catalyzed click reactions of azides and alkynes for covalent layer-by-layer grafting on polyethylene is described. Water-soluble poly(N-alkylacrylamide) copolymers that contain pendant azide or alkyne groups that can be thermally separated from aqueous solutions were used to alternately click together azide and alkyne polymers via 1,2,3-triazole formation onto a prefunctionalized alkyne-containing surface. The layer-by-layer self-assembly process proceeds under ambient conditions and was followed by ATR-IR spectroscopy using control reactions to show that azide groups and copper catalysis are required for the assembly process. Post-graft functionalization of the hyperbranched assembly is used to demonstrate that the functional interfaces so formed can be further derivatized for other functions.
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