Journal
ORGANOMETALLICS
Volume 26, Issue 16, Pages 3918-3924Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om070143v
Keywords
-
Categories
Ask authors/readers for more resources
Thermodynamic data for hydride complexes of the general formula [HNi((P2N2R')-N-R)(2)](BF4), 3, which have been reported previously to function as effective catalysts for the electrochemical oxidation or production of hydrogen, have been determined. Values of Delta G degrees(H+), Delta G degrees(H center dot), and Delta G degrees(H-) have been determined for 3a where R = Cy, R' = Bz, for 3b where R = R' = Ph, and for the new complex 3c, R = Ph, R' = Bz. In addition, the Delta G values for the heterolytic addition of hydrogen to the Ni(II) precursor complexes [Ni((P2N2R')-N-R)(2)](BF4)(2), 1a-c, have been determined experimentally or calculated. The data are useful for understanding the factors that control the catalytic activities observed for these complexes and for the design of additional catalysts.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available