Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 129, Issue 30, Pages 9302-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja073269s
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A rhodium phosphinooxazoline system allows for an efficient enantioselective desymmetrization of dimethyl glutaric anhydride. Both commercially available and in situ generated sp(3)-organozinc nucleophiles couple efficiently in high enantiomeric excess. This chemistry has also been extended to other 3,5-disubstituted anhydrides, and further elaboration has enabled the synthesis of potentially useful syn-deoxypolypropionate fragments.
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