Journal
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
Volume 273, Issue 1-2, Pages 230-239Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2007.04.011
Keywords
3-vinyl indoles; oxidative coupling; palladium-copper catalysts; zeolites
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A new palladium/copper catalytic procedure for the C-3-alkenylation of free NH-indoles is reported. Using homogeneous or heterogeneous hetero-bimetallic [Pd/Cu] -catalysts under mild reaction conditions (10 mol% Pd-catalyst and 10 mol% Cu-catalyst, 70 degrees C, air), substituted indoles are fully (58-82% isolated yields) and selectively (75-100% selectivity) converted to the expected 2-substituted-3-vinyl indoles. (C) 2007 Elsevier B.V. All rights reserved.
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