Journal
BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY
Volume 71, Issue 8, Pages 2046-2051Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1271/bbb.70283
Keywords
sundiversifolide; allelopathic agent; sesquiterpene; Claisen rearrangement
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A new and concise synthesis of (+/-)-sundiversifolide (1), an allelopathic bisnor-sesquiterpene lactone isolated from germinating sunflower (Helianthus annuus L.) seeds, was achieved by employing Lewis acid-mediated Claisen rearrangement as the key step.
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