Journal
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
Volume 406, Issue 9-10, Pages 2239-2259Publisher
SPRINGER HEIDELBERG
DOI: 10.1007/s00216-013-7522-9
Keywords
High-resolution continuum source; Atomic absorption spectrometry; Molecular absorption spectrometry; Graphite furnace; Flame; Determination of non-metals; Determination of metalloids
Funding
- Spanish Ministry of Economy and Competitiveness [CTQ2012-33494, CTQ2009-08606]
- Aragon Government (Fondo Social Europeo)
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This work examines the new possibilities introduced with the arrival of commercially available high-resolution continuum source atomic absorption spectrometers for the determination of metalloids ( B, Si, Ge, As, Se, Sb and Te) and non-metals ( P, S, F, Cl, Br, I and N-based species), such as the improved potential to detect and correct for spectral overlaps and the strategies available to correct for matrix effects. In particular, and considering the increasing number of papers reporting on the use of molecular absorption spectrometry using graphite furnaces and flames as vaporizers, the work discusses in detail the advantages and limitations derived from the monitoring of molecular spectra from a practical point of view, in an attempt to guide future users of the technique.
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