Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 7, Issue 39, Pages 21657-21661Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.5b06830
Keywords
silver nanowires; transparent electrodes; Ag-C bonds; electrografting; XPS; surface functionalization
Funding
- Max-Planck Society for a Post-Doctoral fellowship
- German research foundation (DFG)
- German Research Foundation (DFG) in the frame of the research unit FOR1616
- DFG
- European Commission [280566-UnivSEM]
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Silver nanowires (Ag-NW) assembled in interdigitated webs have shown an applicative potential as transparent and conducting electrodes. However, upon integration in practical device designs, the presence of silver oxide, which instantaneously forms on the Ag-NW surfaces in ambient conditions, is unwanted. Here, we report on the functionalization of Ag-NWs with 4-nitrophenyl moieties through A-C bonds using a versatile two step reduction process, i.e., ascorbate reduction combined electrografting. We show that 40% of the Ag atop sites were terminated and provide high surface stability toward oxidation for more than 2 months while keeping the same intrinsic conductivity as in bulk silver.
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