Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 32, Issue 12, Pages 1749-1754Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2006.11.036
Keywords
Co-B catalyst; hydrogen generation; NaBH4
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Funding
- National Research Foundation of Korea [과C6A1901] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A Co-B catalyst is used to generate hydrogen from alkaline aqueous NaBH4 solutions. This study examined the properties of a CO-B catalyst prepared using different precursors (COCl2 and CoSO4) and NaBH4/CO2+ mole ratios (0.67, 1.5, 3) at calcination temperatures of 130, 250 and 450 degrees C. As the calcination temperature was increased in N-2 atmosphere mixed with 1% air, the typical amorphous structure of Co-B disappeared and the X-ray diffraction peaks corresponding to Co3O4 became sharper. Metallic Co was formed when a NaBH4/CO2+ mole ratio of 3 was used as the reductant with a corresponding reduction in the rate of H-2 generation. The highest level of H-2 generation (2400 ml/min g) was obtained with CoCl2 as the precursor, a NaBH4/CO2+ mole ratio of 1.5 as the reductant, and a calcination temperature of 250 degrees C. (C) 2006 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
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