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Resonance-enhanced multiphoton ionization with circularly polarized light: chiral carbonyls

Journal

ANALYTICAL AND BIOANALYTICAL CHEMISTRY
Volume 405, Issue 22, Pages 6913-6924

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s00216-012-6666-3

Keywords

Chiral analysis; Mass spectrometry/inductively coupled plasma mass spectrometry; Laser spectroscopy; Spectroscopy/instrumentation

Funding

  1. German Research Community (DFG)
  2. European Research Council

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An introduction to the principle and possibilities of the new method of circular dichroism laser mass spectrometry is given and its state of development is reviewed. This method allows enantiosensitive, mass-selective probing of chiral molecules. It is based on the combination of resonance-enhanced multiphoton ionization with circularly polarized light and specially modified time-of-flight mass spectrometry. As an example, application to carbonyls is presented.

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