Journal
CHINESE JOURNAL OF CHEMISTRY
Volume 25, Issue 8, Pages 1082-1084Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.200790201
Keywords
radical yield; ozonolysis; ethene; flow tube; PERCA
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The production of radicals in the ozonolysis of ethene in air in a flow tube was monitored directly by a chemical amplification instrument at room temperature (298 2) K and 1 X 10(5) Pa. The radical yield is 0.50 +/- 0.08 (sigma) and found to be independent of CO. The result shows that the indirectly measured radical yields for the ozonolysis of ethene may be underestimated by a factor of 2.
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