4.7 Article

Microwave-assisted sol-gel synthesis for molecular imprinting

Journal

ANALYTICAL AND BIOANALYTICAL CHEMISTRY
Volume 396, Issue 4, Pages 1607-1612

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s00216-009-3311-x

Keywords

Molecular imprinting; Microwave-assisted; Sol-gel

Funding

  1. Center for Advanced Study, the Department of Chemistry
  2. University of Illinois
  3. U.S. Department of Energy [DE-FG02-07ER46453, DE-FG02-07ER46471]

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Molecularly imprinted polymers have been the subject of intense research for several decades in both academic and industrial settings. In this paper, we introduce a novel microwave-assisted sol-gel method for molecular imprinting of silica microspheres. The microspheres were characterized, and their adsorption of imprint and non-imprint molecules was investigated. The dye molecules methyl orange and ethyl orange were used as templates. Good molecular imprinting was observed as evaluated by the re-adsorption of dye into the silica matrix followed by the removal of dye from the supernatant solution.

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