4.2 Article

Investigation into the ROMP copolymerization of peptide- and PEG-functionalized norbornene derivatives

Journal

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 45, Issue 15, Pages 3178-3190

Publisher

WILEY
DOI: 10.1002/pola.22068

Keywords

copolymerization; peptides; poly(vinyl ethers); ROMP

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The ring-opening metathesis polymerizations (ROMP), using RuCl2 (PCY3)(2)CHPh, of a series of peptide-functionalized norbornene derivatives have been investigated. Incorporation of a PEG-monomer was found to prevent premature precipitation of polymer strands during the course of polymerization reactions and yield water compatible polymers in high conversions. (c) 2007 Wiley Periodicals, Inc.

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