Abatement and degradation pathways of toluene in indoor air by positive corona discharge

Indoor air concentrations of volatile organic compounds often exceed outdoor levels by a factor of 5. There is much interest in developing new technologies in order to improve indoor air quality. In this work non-thermal plasma (DC positive corona discharge) is explored as an innovative technology for indoor air purification. An inlet gas stream of 10 1 min(-1) containing 0.50 +/- 0.02 ppm toluene was treated by the plasma reactor in atmospheric conditions. Toluene removal proved to be achievable with a characteristic energy density ro of 50 J 1(-1). Removal efficiencies were higher for 26% relative humidity (epsilon(0) = 35 J 1(-1)), compared with those at increased humidities (50% relative humidity, epsilon(0) = 49 J 1(-1)). Reaction products such as formic acid, benzaldehyde, benzyl alcohol, 3-methyl-4-nitrophenol, 4-methyl-2-nitrophenol, 4-methyl-2-propyl furan, 5-methyl-2-nitrophenol, 4-nitrophenol, 2-methyl-4,6-dinitrophenol are identified by means of mass spectrometry. Based on these by-products a toluene degradation mechanism is proposed. (C) 2007 Elsevier Ltd. All rights reserved.