Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 606, Issue 1, Pages 55-62Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2007.04.014
Keywords
Prussian blue; electrochemical deposition; ferricyanide; HAuCl4; cyclic voltammetry; composite ceramic carbon electrode
Categories
Ask authors/readers for more resources
A new method for rapid electrochemical deposition of a compact and thick Prussian blue film on the composite ceramic carbon electrode (CCE) surface from a single ferricyanide solution in the presence of HA(u)Cl(4) was investigated by electrochemical and SEM techniques. The nature of the electrode material and experiment conditions such as the effect of pH, concentration of HAuCl4 as well as the initial concentration of ferricyanide were also studied carefully. The results showed that the formation rate of Prussian blue on the CCE surface was dramatically improved with the addition of HAuCl4. Compared to other substrate material, the formation rate of Prussian blue on the CCE surface from a single acid ferricyanide solution in the presence of HAuCl4 was higher due to the porosity of the sol-gel material and the surface roughness. Furthermore, this Prussian blue modified electrode showed high stability and excellent electrocatalytic activity to hydrogen peroxide. The present method was convenient and rapid for the preparation of a compact and thick Prussian blue film compared to other method reported previously. (c) 2007 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available