4.2 Article

Thermodynamic description of SrO-Al2O3 system and comparison with similar systems

Journal

JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION
Volume 28, Issue 4, Pages 362-368

Publisher

ASM INTERNATIONAL
DOI: 10.1007/s11669-007-9086-x

Keywords

phase diagram; SrO-Al2O3; thermodynamic properties

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The Al2O3-SrO binary system has been studied using the CALPHAD technique in this paper. The modeling of Al2O3 in the liquid phase is modified from the traditional formula with the liquid phase represented by the ionic two-sublattice model as (Al3+, Sr2+)(P) (AlO21-, O2-)(Q). Based on the measured phase equilibrium data and experimental thermodynamic properties, a set of thermodynamic functions has been optimized using an interactive computer-assisted analysis. The calculated results are compared with experimental data. A comparison between this system and similar systems is also given.

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