Journal
ORGANIC LETTERS
Volume 9, Issue 16, Pages 3187-3190Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol071331k
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- NIGMS NIH HHS [GM-47480] Funding Source: Medline
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[GRAPHICS] A readily available and simple (MW = 444.5 g/mol) valine-based chiral phosphine is used to promote highly efficient catalytic asymmetric conjugate additions of dialkyl- and diarylzinc reagents to acyclic beta-silyl-alpha,beta-unsaturated ketones. The catalytic asymmetric protocol allows access to versatile allylsilanes that bear a trisubstituted olefin in high diastereo- and enantiomeric purity.
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