Journal
ORGANIC LETTERS
Volume 9, Issue 16, Pages 3089-3092Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol071168t
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[GRAPHICS] The Ir-catalyzed enantioselective hydrogenation of various N-(3,5-dimethyl-4-methoxy)phenylimines was performed under mild conditions in the presence of new P,N-ferrocenyl iridium complexes leading to (R)-N-(3,5-dimethyl-4-methoxy)phenylamines in high yields and enantioselectivities (up to 99%). These chiral aryl amines can be readily deprotected using Ce(NH4)(2)(NO3)(6).
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