Journal
ADVANCED MATERIALS
Volume 19, Issue 15, Pages 2023-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.200700457
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Slide-ring topological gels with mobile cross-linking units are a new class of soft materials that exhibit distinct features differing from those of conventional chemically or physically crosslinked gels. Photoresponsive behavior arising from the dynamic nature of the cross-linkers is demonstrated for a slide-ring, gel prepared by adding azobenzene units to the mobile a-cyclodextrin units of a poly(ethylene oxide)based polyrotaxane (see figure).
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