Journal
TETRAHEDRON LETTERS
Volume 48, Issue 32, Pages 5669-5671Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.06.034
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We report a novel, facile and asymmetric approach for the synthesis of the indole alkaloid (+)-harmicine via a highly diastereoselective N-acyliminium cyclization reaction as a key synthetic step, and verify the relative stereochemistry of the key synthetic intermediate in this approach through X-ray crystallography. Crown Copyright (c) 2007 Published by Elsevier Ltd. All rights reserved.
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