Journal
ANALYTICA CHIMICA ACTA
Volume 713, Issue -, Pages 56-62Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2011.11.024
Keywords
1-Hexyl-3-methylimidazolium hexafluorophosphate; Ionic liquid; Microextraction; Cobalt; Nutritional supplements
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Funding
- Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET)
- Agencia Nacional de Promocion Cientifica y Tecnologica (FONCYT) (PICT-BID)
- Universidad Nacional de Cuyo (Argentina)
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In the present work, a simple and rapid analytical method based on application of ionic liquids (ILs) for inorganic Co(II) species (iCo) microextraction in a variety of nutrient supplements was developed. Inorganic Co was initially chelated with 1-nitroso-2-naphtol (1N2N) reagent followed by a modern technique named ultrasound-assisted temperature-controlled ionic liquid dispersive liquid phase microextraction (USA-TILDLME). The extraction was performed with 1-hexyl-3-methylimidazolium hexafluorophosphate [C(6)mim][PF6] with the aid of ultrasound to improve iCo recovery. Finally, the iCo-enriched IL phase was solubilized in methanol and directly injected into an electrothermal atomic absorption spectrometer (ETAAS). Several parameters that could influence iCo microextraction and detection were carefully studied. Since the main difficulty in these samples is caused by high concentrations of potential interfering ions, different approaches were evaluated to eliminate interferences. The limit of detection (LOD) was 5.4 ng L-1, while the relative standard deviation (RSD) was 4.7% (at 0.5 mu g L-1 Co level and n=10), calculated from the peak height of absorbance signals. Selective microextraction of iCo species was achieved only by controlling the pH value during the procedure. The method was thus successfully applied for determination of iCo species in nutritional supplements. (C) 2011 Elsevier B.V. All rights reserved.
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