Journal
ORGANIC LETTERS
Volume 9, Issue 17, Pages 3253-3254Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol7016092
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The first iron-catalyzed cross-coupling reaction between alkenyl Grignard reagents and n- or s-alkyl bromides is described. The reaction is stereoselective and takes place in the presence of 5 mol % of [Fe(acac)(3)/TMEDA/HMTA] (1:2:1) under very mild conditions (THF, 0 degrees C, 45 min).
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