4.7 Article

Pd-C-induced catalytic transfer hydrogenation with triethylsilane

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 17, Pages 6599-6601

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo0706123

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Funding

  1. NCI NIH HHS [CA016672, CA096652] Funding Source: Medline

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In situ generation of molecular hydrogen by addition of triethylsilane to palladium-charcoal catalyst results in rapid and efficient reduction of multiple bonds, azides, imines, and nitro groups, as well as benzyl group and allyl group deprotection under mild, neutral conditions.

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