Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 72, Issue 17, Pages 6473-6480Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo070923d
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Funding
- NIGMS NIH HHS [GM57873, GM072495] Funding Source: Medline
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The total synthesis of racemic terpestacin and 11-epi-terpestacin using the allene ether Nazarov reaction as the key step is described. All stereochemistry is derived from the stereogenic carbon atom that is formed during the Nazarov reaction.
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