Journal
ANALYTICA CHIMICA ACTA
Volume 726, Issue -, Pages 93-101Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2012.03.027
Keywords
NiO thin films; Sputtering; Mobility; Glucose; Biosensor
Categories
Funding
- UGC
- DST, Government of India
- CSIR
- University of Delhi
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RF sputtered p-type nickel oxide (NiO) thin film exhibiting tunable semiconductor character which in turns enhanced its functional properties. NiO thin film with high hole mobility is developed as a potential matrix for the realization of glucose biosensor. NiO thin film prepared under the optimized deposition conditions offer good electrical conductivity (1.5 x 10(-3) Omega(-1)-cm(-1)) with high hole mobility (2.8 cm(2) V(-1)s(-1)). The bioelectrode (GO(x)NiO/ITO/glass) exhibits a low value of Michaelis-Menten constant (K-m = 1.05 mM), indicating high affinity of the immobilized GO(x) toward the analyte (glucose). Due to the high surface coverage (2.32 x 10(-7) mol cm(-2)) of the immobilized enzyme on to the NiO matrix and its high electrocatalytic activity, the prepared biosensor exhibits a high sensitivity of 0.1 mA (mM(-1)-cm(-2)) and a good linearity from 25 to 300 mg dL(-1) of glucose concentration with fast response time of 5 s. Various functional properties of the material (mobility, crystallinity and stress) are found to influence the charge communication feature of NiO thin film matrix to a great extent, resulting in enhanced sensing response characteristics. (c) 2012 Elsevier B.V. All rights reserved.
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