Journal
INORGANIC CHEMISTRY
Volume 46, Issue 17, Pages 6846-6848Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic701256e
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Ethylenediaminetetraacetate is converted into its triacetate by peroxotitanate(IV), and strong chelation of the triacetate ligand to the metal center facilitates elimination of the pendant acetoxylate group. Various species of peroxotitanium(IV) complexes in the reaction sequence are fully characterized.
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