Journal
TETRAHEDRON
Volume 63, Issue 34, Pages 8282-8285Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2007.05.103
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Chemical investigation on the gorgonian coral Briareum sp. has led to the isolation of six oxygenated briaran diterpenes 1-6, including three new compounds briarenolides A-C (1-3). The structures of 1-3 were determined on the basis of extensive spectroscopic analysis and by comparison of their spectral data with those of related metabolites. Among these metabolites, 1 and 2 are rarely found 9-ketobriaranes. Also, 1 is the first briarane derivative possessing a 20-hydroxy group. (c) 2007 Elsevier Ltd. All rights reserved.
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