4.4 Article

The synthetic potential of graphite-catalyzed alkylation

Journal

TETRAHEDRON
Volume 63, Issue 34, Pages 8351-8357

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2007.05.005

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Unmodified graphite is introduced as a mild catalyst for alkylation of aromatic compounds and primary alcohols, applicable when utilization of strong Lewis acids is not feasible. The electrophilic intermediate has a significant carbocationic character and can be formed on a partially rate-limiting step. (c) 2007 Elsevier Ltd. All rights reserved.

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