Journal
TETRAHEDRON LETTERS
Volume 48, Issue 34, Pages 6005-6009Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.06.134
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The first total synthesis of pelargonidin 3-O-6 ''-O-acetyl-beta-D-glucopyranoside, an acylated anthocyanin of magenta-col-ored Verbena flowers, was successfully carried out. The key intermediate, protected kaemferol 3-O-glucoside, was constructed by the Baker-Venkataraman rearrangement from a glycosyloxyacetophenone followed by Zn-Hg reduction to the corresponding acylated anthocyanin. (C) 2007 Elsevier Ltd. All rights reserved.
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