Journal
TETRAHEDRON
Volume 63, Issue 34, Pages 8305-8310Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2007.05.088
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Conjugate additions of non-nucleophilic N-containing compounds such as amides, thioamides, sulfonamides, and electron- poor anilines with different Michael acceptors can be promoted through the use of tributylphosphine. The range of useful pK(a)'s of nucleophiles has been established (pK(a)< 25) and new insights into the mechanism proposed. (c) 2007 Elsevier Ltd. All rights reserved.
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