Journal
MACROMOLECULES
Volume 40, Issue 17, Pages 6181-6189Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ma070442w
Keywords
-
Categories
Ask authors/readers for more resources
Amphiphilic, RAFT-capped, (acrylic acid)(x)(styrene)(y) diblock copolymers (x congruent to 10, y = 10, 5, 0) were synthesized and used as stabilizers in emulsion polymerization. Above the critical micelle concentration (cmc) of the diblocks and under appropriate reaction conditions micelles of the more hydrophobic diblocks were sufficiently nonlabile to be nucleated and act as seed particles for latex particle formation. The key parameters which allow control over the system are diblock hydrophobicity and initiator concentration. A homogeneous nucleation mechanism is most likely to operate below the cmc of the diblocks.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available