Journal
ORGANOMETALLICS
Volume 26, Issue 18, Pages 4376-4378Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om700418h
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A homocoupling of p-xylene to afford biaryl- or diarylmethane as a major product has been carried out in a catalytic system of Pd(OAc)(2)/CF3CO2H (TFA)/K2S2O8. In this coupling reaction, the aryl and benzylic C-H bonds of p-xylene can be selectively activated just by tuning the concentration of TFA.
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