Journal
ORGANIC LETTERS
Volume 9, Issue 18, Pages 3643-3645Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol701521k
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A beta-tetrapeptide made up of homochiral cyclobutane residues displays conformational bias in solution prompted by the formation of intramolecular hydrogen bonds. Moreover, this compound self-assembles to produce nanosized fibrils and, in some media, it also forms a gel. The combination of NMR, TEM, AFM, and theoretical calculations has proven to be very useful in obtaining insight into the details of these new structures.
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